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Beilstein J. Org. Chem. 2015, 11, 1494–1502, doi:10.3762/bjoc.11.162
Graphical Abstract
Scheme 1: Borylation of aryldiazonium tetrafluoroborates 3. Reaction conditions: 3 (1 mmol), B2pin2 (1 mmol),...
Scheme 2: Proposed reaction mechanism.
Scheme 3: Reaction of diazonium salt 3i under borylation conditions.
Scheme 4: Suzuki–Miyaura reaction of boronates 2a and 2b with aryl iodides. Reaction conditions: 2 (1 mmol), ...
Scheme 5: Syntesis of boronic acid 8b and trifluoroborates 9. Reaction conditions for the synthesis of 8b: 2 ...
Scheme 6: Iodination of aryldiazonium tetrafluoroborates 3. Reaction conditions: 3 (1 mmol), I2 (1.1 mmol), p...
Beilstein J. Org. Chem. 2012, 8, 1185–1190, doi:10.3762/bjoc.8.131
Scheme 1: Proposed synthesis of alkenyl-(pentafluorosulfanyl)benzenes.
Scheme 2: Reactive intermediates involved in HWE reactions to alkenes 5 and 6.
Scheme 3: Diazotization/reduction of 8d to 9d and the formation of unexpected cyclized product 10d.
Scheme 4: Synthesis of substituted phenanthrene 11d.
Scheme 5: Synthesis of phosphonate 12 and SF5-stilbene derivative 13d.